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| (1)Technical Research for CCT Development |
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| We have been commissioned by Ministry of Economy, Trade and Industry (METI) and New Energy and Industrial Technology Development Organization (NEDO) to carry out various surveys into technology that uses coal, such as collecting coal-related data from all over the world. |
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| (2)Clean Coal Technology Development |
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1) New Coke Production Technology (SCOPE21)
(Joint Development with the Japan Iron and Steel Federation)
In order to contribute to reducing the world's environmental problems, we succeeded in developing some groundbreaking coke-manufacturing technology which can cut CO2 by 20% compared with conventional methods.(2003) Applying this technology will not only reduce CO2 emissions, but by blending to 50% of it with steam coal, it will also allow us to cope with the soaring cost of coking coal.Productivity will increase 2.4 times and it is forecast that it will be commercially available in several years, making possible an 18% reduction in the cost of coke production cost. This technology won the Japan Institute of Energy's Technology Prize in 2004.
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2) Efficient Co-Production with Coal Flash Partial Hydro-pyrolysis Technology (ECOPRO)
Coal Flash Partial Hydro-pyrolysis Technology has a high pressure entrained bed reaction furnace
comprising two chambers of the partial oxidation part (the lower part) and the reforming part (the
upper part), and this arrangement gives us high energy efficiency by utilizing heat of high temperature
gas from a gasifier for coal pyrolysis reaction. Further, light oil and hydrogen rich syngas are
produced by one reaction furnace by making the reforming part hydrogen atmosphere. Light oil
becomes chemical raw materials such as high value-added BTX or naphthalene, and a syngas is used
for chemical synthesis (methanol) and clean synthetic fuel (GTL) production and integrated coal
gasification combined cycle (IGCC). Development of various CCT model for the field of chemistry /
electricity / steel is enabled based on this technology. We carry out a operating study after the
completion of a pilot plant in Kitakyushu city in August, 2006 and plan the business promotion that
put international joint demonstration with Asian countries in a field of vision at the same time.
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3) Hydrogen Production by Reaction-Integrated Novel Gasification Process (HyPr-RING)
We have developed a high-efficiency hydrogen production process from coal. The fundamental concept behind the process is the integration of a water-carbon reaction, water-gas shift reaction, and CO2 absorbing reaction in a single reactor, at a temperature of approximately 650℃ and a pressure of 3 MPa or greater. As shown in the diagram, the introduction of coal, an absorbent (CaO), and water into a high-pressure reactor accelerates the decomposition of coal, and, at the same time, the CO2 produced from this is fixed into CaCO3 by the absorbent. The subsequent reaction resolves the water to produce a large amount of hydrogen. After CaCO3 is calcinated, the CaO is again put into the reactor with the coal and the CO2 can be recovered.
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4) Hyper Coal developing
We are developing ashless coal (hyper coal), in which the ash content and alkali concentration are
very low, by processing the coal with ion exchange and solvent extraction and researching
applications for pulverized coal-fired power generation, gas turbine, a raw material for coal
gasification, agent for metallurgical refining and binder for coke production.
For a combined cycle power generation system to burn it directly with a gas turbine, we expect to
achieve a net efficiency of 48%. The amount of hyper coal by means of solvent extraction is about
60% of the original coal and the
remaining 40% of the coal
becomes residual coal with an ash content of about 15%.
This residual coal can be used in
existing thermal power systems
with pulverized coal combustion.
The overall efficiency when using
both the hyper coal and the
residual coal is expected to be 45
%, and the emission of CO2 could
be reduced by 13% compared
with existing coal-fired thermal
power generation.
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5) CO2 Capture from pulverized coal fired power station by apllying Oxy-fuel Combustion
We are working on a series of joint demonstration tests with Australia using oxy-fuel combustion
at an existing coal fired power station (Callide A power plant in Australia) to capture CO2, and
inject and fix it underground.
This is the world’s first demonstration test of the CO2 capture and
storage (CCS) technique that sequesters CO2 from a coal fired power station. The demonstration
test was selected as a Flagship Project of the Asia Pacific Partnership (APP) on Clean
Development and Climate.
When the CCS technique is applied, coal fired power plants will use oxygen to burn coal instead
of air which is usually used. Most of the flue gas discharged from this combustion system is CO2,
which can be easily separated and
captured. For this flue gas, smaller
SOx and NOx removal systems are
needed or can even be eliminated.
The technique allows low-cost CO2
recovery in both existing and new
power plants and CO2 storage in
coal beds or underground aquifers.
This will achieve clean coal-fired
power generation free of CO2.
(This technique won a prize from
the Combustion Society of Japan.)
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6) Development of Next-generation IGCC / IGFC (A-IGCC / A-IGFC)
Coal gasification technology can combine high efficiency with zero emissions. With coal
gasification technology at the core, we can look forward to developments in diversified CCT
model trials, such as high-efficiency IGCC and IGFC, the production of hydrogen, methanol, and
DME, and the combined production of electric power with chemicals and iron.
Instead of conventional IGCC and IGFC that integrate the partial combustion gasification
furnace, solid fuel cells, steam turbines, and gas turbines in a cascade pattern, we are currently
pressing ahead with developing
the technology for A-IGCC
and A-IGFC that reuse the
exergy, recycling the exhaust
heat of the gas turbine or solid
fuel cell in an endothermic
reaction within a steam
reforming gasification furnace.
It is estimated that recycling
the exergy will improve
efficiency by about 10%, and it is
attracting attention as a process
for reducing emissions to zero,
with easy separation, collection,
and fixation of CO2, and use of
versatile energy sources.
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